[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
[1,1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II)
CAS: 67292-34-6
Molecular Formula: C34H22Cl2FeNiP2
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) - Names and Identifiers
| Name | [1,1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II) |
| Synonyms | DPPF·NICL2 Ni(dppf)Cl2 Dichlorobisdiphenylphosphinoferrocenenickel (1,1'-bis(diphenylphosphino)ferrocene)-dichloroni 1,1'-Bis(diphenylphosphino)ferrocenedichloronickel 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE Dichloro[1,1-bis(diphenylphosphino)ferrocene]nickel(II) [1,1-Bis(diphenylphosphino)ferrocene]dichloronickel(II) [1,1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II) [1, 1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II) DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLORONICKEL(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]Nickle (II) [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) DICHLORIDE |
| CAS | 67292-34-6 |
| InChI | InChI=1/2C17H14P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2 |
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) - Physico-chemical Properties
| Molecular Formula | C34H22Cl2FeNiP2 |
| Molar Mass | 677.94 |
| Melting Point | 285°C (dec.)(lit.) |
| Water Solubility | Insoluble in water. |
| Appearance | crystal |
| Color | green micro |
| Exposure Limit | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Storage Condition | Inert atmosphere,Room Temperature |
| Sensitive | Sensitive to air |
| MDL | MFCD00270284 |
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | R45 - May cause cancer R42/43 - May cause sensitization by inhalation and skin contact. |
| Safety Description | S53 - Avoid exposure - obtain special instructions before use. S22 - Do not breathe dust. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | 2811 |
| WGK Germany | 3 |
| HS Code | 29319090 |
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) - Introduction
[1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) is a binuclear transition metal compound, also known as [(dppe)FeCp]NiCl2. Its chemical formula is NiCl2[(dppe)FeCp], where Ni stands for nickel, Cp stands for metallocene, and dppe stands for biphenylphosphine. The compound has the following properties:
1. Appearance:[1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) is a red to brown crystalline powder.
2. Thermal stability: The compound is relatively stable at high temperatures and can be heated to 300°C under anhydrous conditions.
3. Solubility:[1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) is easily dissolved in common organic solvents, such as toluene, dimethylformamide, etc.
4. Transition metal coordination: Because the compound contains two transition metal elements (nickel and iron), it can be used as a bimetallic ligand for the synthesis of other polynuclear transition metal compounds.
[1,1 '-Bis(diphenyphosphino)ferrocene] The use of dichloronickel(II) is mainly concentrated in the study of transition metal coordination chemistry, such as catalyst design and preparation of synthetic catalysts. It can play an important role as a catalyst precursor or ligand in different catalytic reactions, such as hydrogenation, oxidation, carbonylation, coupling reactions, etc.
The preparation method of this compound usually involves a synthetic liquid phase coordination chemistry method, which can be obtained by reacting nickel dichloride and [(dppe)FeCp] in an appropriate solvent. The specific preparation method can be optimized and improved as needed.
When using and handling this compound, you need to pay attention to the following safety information:
1. [1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) may be toxic to humans, irritating and corrosive.
2. In the process of operation and handling, it is necessary to take appropriate protective measures, such as wearing protective glasses, gloves and laboratory clothes. Avoid contact with skin and eyes, avoid inhaling its dust or gas.
3. The compound should be stored in a dry, cool and well-ventilated place, away from fire and oxidizing agents.
4. When disposing of waste, it should comply with relevant regulations and treat it as toxic chemical waste.
1. Appearance:[1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) is a red to brown crystalline powder.
2. Thermal stability: The compound is relatively stable at high temperatures and can be heated to 300°C under anhydrous conditions.
3. Solubility:[1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) is easily dissolved in common organic solvents, such as toluene, dimethylformamide, etc.
4. Transition metal coordination: Because the compound contains two transition metal elements (nickel and iron), it can be used as a bimetallic ligand for the synthesis of other polynuclear transition metal compounds.
[1,1 '-Bis(diphenyphosphino)ferrocene] The use of dichloronickel(II) is mainly concentrated in the study of transition metal coordination chemistry, such as catalyst design and preparation of synthetic catalysts. It can play an important role as a catalyst precursor or ligand in different catalytic reactions, such as hydrogenation, oxidation, carbonylation, coupling reactions, etc.
The preparation method of this compound usually involves a synthetic liquid phase coordination chemistry method, which can be obtained by reacting nickel dichloride and [(dppe)FeCp] in an appropriate solvent. The specific preparation method can be optimized and improved as needed.
When using and handling this compound, you need to pay attention to the following safety information:
1. [1,1 '-Bis(diphenyphosphino)ferrocene]dichloronickel(II) may be toxic to humans, irritating and corrosive.
2. In the process of operation and handling, it is necessary to take appropriate protective measures, such as wearing protective glasses, gloves and laboratory clothes. Avoid contact with skin and eyes, avoid inhaling its dust or gas.
3. The compound should be stored in a dry, cool and well-ventilated place, away from fire and oxidizing agents.
4. When disposing of waste, it should comply with relevant regulations and treat it as toxic chemical waste.
Last Update：2024-04-10 22:29:15
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Product Name: [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Visit Supplier Webpage Request for quotation
CAS: 67292-34-6
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Mobile: 18021002903
QQ: 3008007409
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CAS: 67292-34-6
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
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